Water chemical characteristics
The recorded slightly alkaline pH is preferable in waters for the removal of heavy metals by precipitation as carbonate or bicarbonate (Ahipathy and Puttaiah 2006). The pH was relatively high in winter, because the water stays longer in contact with bottom sediment owing to the low flow rate and shallow water column. With respect to TDS, the water samples are considered good potable water with values < 500 ppm. A higher level of TDS during the winter season can be attributed to untreated agricultural and domestic wastes discharged into the river, as well as water longer contact with bottom sediment. Samples (23) and (24) were collected near agricultural drains while the sample (26) at Gerga Sugar factory. The water longer contact with bottom sediment was the main reason in the elevated concentrations of Mg, Na, K, HCO3, SO4, and NO3 during winter than summer. The appearance of NO3 in concentrations > 5 ppm is reflecting unsanitary conditions (Uqab et al. 2017) in the Nile water.
With respect to the studied HMs, Pb was the most dominant among all the metals studied in the collected water samples at different stations. The noticed low Pb concentration during the winter season compared to the summer season (Fig. 3a) may result from the human activities during summer such as navigation, traffic, wastewater effluents, and urban runoff. The spill of fuel and traffic exhaust can produce a considerable concentration of Pb (Elnazer et al. 2015). The Pb was detected as a pollutant for the River Nile from several decades, where 24 μg/l was recorded in 1987 (Lasheen 1987) and about 214.3 μg/l in 2009 (Toufeek 2011). Narrow ranges of Cd (bdl-4 and 1–5 μg/l in winter and summer, respectively) were recorded in the studied samples with noticed higher concentrations during summer than winter (Table 2, Fig. 3d). The higher concentration of Cd in the summer season might have resulted from the sediments of Lake Nasser, which contains about 0.175 μg/g of Cd (Goher et al. 2014). Also, navigation, agricultural runoff, and sewage effluents discharge to the water courses contributed to the Cd load in this season.
Arsenic was detected only in about 36.7% of the studied samples. These results support the anthropogenic source of As in the study area water. The highest concentrations were recorded in Qena city (samples 8, 9, and 10), in agricultural drains (samples 14, 24, and 30), and at navigation sites (samples 4 and 20). The increase of As during summer than winter (Fig. 3e) might be due to the high and intensive activities during summer than winter such as navigation. The marked variation in As concentrations proposed intermixed sources in the study area including, to great extent, the role of human activities and to a limited extent the role of the natural process, especially the occasionally storms, which carry considerable amounts of sediments from the Eastern Desert mountains, where some rocks in the Eastern Desert contain up to 75 mg/kg of As (Sadek et al. 2015).
The mostly affected metal with seasonal variation was Cr; its concentration (Table 2) during summer (288.2 μg/l) was 12 times its concentration during winter (23.1 μg/l). The observed higher concentration of Cr during summer was mainly carried from the Ethiopian lands with water as a result of the dissolution of ferromagnesian minerals by rains in the Ethiopian mafic/ultramafic rocks (Omer, 1996). Copper was not detectable in > 50% of the samples collected during summer and 30% of the samples collected during winter. The reports show that sites with a low concentration of Cu had high Ca levels (Suresh 2008); this is supported by the negative correlation between Ca and Cu during the current study (Fig. 4) as a result of ion-exchange. The absence of Cu from about 50% of the studied samples during summer could be attributed to the high flow rate and volume of water, which led to the low interaction between sediments and water.
The recorded low concentrations of Zn can be attributed to its absorbance by bottom sediment (Singh 2005, Kabata-Pendias and Mukherjee 2007). The higher Zn concentration in summer than winter (Fig. 4f) might result from the small water column and slow flow-rate during winter, where Zn is mainly absorbed on the mineral grains. Also, lower pH values during summer than winter enhance the solubility of Zn (Singh 2005). Other sources of Zn into aquatic ecosystems include urban runoff, fertilizers, and municipal sewage (Kabata-Pendias and Mukherjee 2007, Damodharan 2013). Generally, the variation in the concentrations of the studied elements from site to another is mostly related to human activities (industrial, agricultural, urban runoff, traffic, etc.), which differentiate from location to another and also from winter to summer.
Evaluation of water for drinking
The results indicated the suitability of water for drinking purposes with respect to pH, TDS, Ca, Mg, Na, HCO3, SO4, Cl, NO3, Cu, and Zn was within the permissible limits of WHO (2011) during the two seasons (Tables 1 and 2). Also, most of the studied samples contain acceptable levels of As (19 samples in winter and 19 samples in summer), Cd (28 samples in winter and 21 samples in summer), and Cr (28 samples in winter). On the other hand, the water samples contained unacceptable concentrations Pb (during winter and summer) and Cr (during summer).
The presence of the unacceptable concentrations of some metals in the River Nile water might cause health problems, because in Egypt, there are two types of water treatment plants (conventional and compact). The main step in the two types is the use of alum as a coagulant (Donia 2007). Unfortunately, the use of alum as coagulant had led to the appearance of high Al (the major component value in alum) concentrations in the domestic tap water (DWAF 1996). The presence of Al in water may cause Alzheimer’s disease and carcinogenic effects. In addition, the percentage removal of the metals from raw water samples increased with mg/l dosage of coagulant. The efficiency of removal for As, Cd, Cr, Cu, Mn, Ni, and Zn was 3.7, 5.88, 85.42, 4.63, and 47.37%, respectively, at 10 mg/l dose of Al2(SO4)3 (Fatoki and Ogunfowokan 2002). This indicates that till after treatment process toxic levels of metals may reach the end consumers of water causing many health problems. Therefore, more attention should be given to the presence and sources of these elements in drinking water by the governmental authorities.
Evaluation of water for irrigation
All the samples collected during this study had TDS < 500 ppm and considered excellent for irrigation without any detrimental effect according to Richards (1954). Also, all the samples collected during this study had SAR < 10 (Table 1) and can be used safely for all types of soil based on Richards (1954) classification of SAR. In addition, the studied water samples contain acceptable concentrations of the studied metals, except the recorded As (during winter and summer) and Cr (during summer only) in comparison with NAS-NAE (1972) allowable levels of HMs.