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Table 5 Thermal properties of starches modified with sucrose

From: Sucrose- and formaldehyde-modified native starches as possible pharmaceutical excipients in tableting

Parameter

Thermal property (value) per %

Maize

Thermal property (value) per %

Rice

2.5%

5%

10%

20%

25%

40%

2.5%

5%

10%

20%

25%

40%

Various concentrations of the cross-linking agent used

            

 Tg Onset temp (°C)

37.3

33.7

62.9

3.9

ND

40.8

47.0

28.1

22.3

17.9

14.7

10.8

 Tg Endset temp (°C)

13.1

55.5

73.8

65.4

ND

29.8

50.4

40.7

37.2

31.9

27.6

19.5

 ∆H (Delta Cp) (J/(gk))

0.294

16.55

4.96

163.30

ND

3.642

14.77

18.88

20.54

23.82

29.63

32.28

 Melting/Endothermic (Peak Temp) (°C)

297.4

281.7

294.7

273.4

ND

215.1

239.3

209.1

187.1

188.5

274.1

222.1

 Peak intensity (m/N/mg)

− 0.25

− 0.90

− 0.52

− 2.65

ND

− 0.52

− 2.20

− 3.65

− 2.25

− 3.81

− 3.20

− 3.90

  1. KEY: Tg = Glass Transition; ∆H = Energy change; ND = Not determined