Compound | RT | RI | Treatments | ||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
T1 | T2 | T3 | T4 | T5 | T6 | T7 | T8 | T9 | |||
Tricyclene | 5.8 | 919 | 0.375 ± 0.02ab | 0.390 ± 0.014ab | 0.309 ± 0.007cd | 0.282 ± 0.012d | 0.275 ± 0.004d | 0.280 ± 0.039d | 0.406 ± 0.04a | 0.353 ± 0.032bc | 0.349 ± 0.023bc |
α-Pinene | 6.3 | 930 | 19.99 ± 1.24ab | 21.64 ± 0.67a | 16.34 ± 0.14d | 12.09 ± 1.08e | 15.99 ± 0.38d | 13.54 ± 1.64e | 19.29 ± 1.70bc | 21.22 ± 1.71ab | 17.84 ± 0.82cd |
Camphene | 6.8 | 944 | 6.19 ± 0.27a | 6.66 ± 0.13a | 4.31 ± 0.24c | 4.16 ± 0.3c | 4.99 ± 0.26b | 3.47 ± 0.52d | 6.27 ± 0.08a | 6.65 ± 0.058a | 4.77 ± 0.29b |
Verbenene | 7.0 | 949 | 0.41 ± 0.007cd | 0.61 ± 0.004ab | 0.49 ± 0.034bc | 0.28 ± 0.12d | 0.61 ± 0.027ab | 0.38 ± 0.13cd | 0.30 ± 0.10d | 0.72 ± 0.036a | 0.61 ± 0.072ab |
β-Pinene | 7.8 | 972 | – | – | – | 0.16 ± 0.004a | 0.13 ± 0.001c | – | – | 0.14 ± 0.004b | – |
1-Octen-3-one | 8.0 | 975 | – | – | – | 0.26 ± 0.008a | 0.21 ± 0.02c | – | 0.23 ± 0.003b | 0.21 ± 0.003c | – |
3-Octanone | 8.3 | 983 | 4.17 ± 0.38a | 2.76 ± 0.10bc | 1.23 ± 0.01e | 2.42 ± 0.10c | 1.89 ± 0.18d | 0.96 ± 0.20e | 3.83 ± 0.43a | 2.91 ± 0.01b | 1.31 ± 0.09e |
β-Myrcene | 8.5 | 989 | 1.94 ± 0.34a | 1.74 ± 0.08a | 1.06 ± 0.11b | 0.57 ± 0.03c | 0.96 ± 0.007b | 0.82 ± 0.20bc | 1.74 ± 0.04a | 1.82 ± 0.20a | 1.16 ± 0.08b |
n-Decane | 8.9 | 998 | 1.90 ± 0.04ab | 1.74 ± 0.14bc | 1.42 ± 0.13d | 1.97 ± 0.01a | 1.78 ± 0.02abc | 1.61 ± 0.22c | 1.87 ± 0.07ab | 1.96 ± 0.07a | 1.73 ± 0.04bc |
α-Terpinene | 9.5 | 1013 | 0.72 ± 0.06a | 0.28 ± 0.08cd | 0.16 ± 0.008e | 0.32 ± 0.024c | 0.17 ± 0.05e | 0.32 ± 0.04c | 0.72 ± 0.13a | 0.18 ± 0.02de | 0.47 ± 0.008b |
p-Cymene | 9.9 | 1021 | 2.94 ± 0.47a | 2.67 ± 0.04a | 1.54 ± 0.15bc | 0.99 ± 0.03d | 1.69 ± 0.04b | 1.19 ± 0.21cd | 2.67 ± 0.43a | 3.03 ± 0.10a | 1.64 ± 0.11b |
1,8-Cineole | 10.2 | 1027 | – | 0.42 ± 0.06a | 0.36 ± 0.06b | 0.32 ± 0.02c | – | 0.32 ± 0.04c | – | – | – |
γ-Terpinene | 11.5 | 1055 | 0.44 ± 0.03a | – | 0.37 ± 0.03b | – | 0.24 ± 0.01d | 0.32 ± 0.04c | 0.38 ± 0.04b | 0.35 ± 0.03bc | 0.35 ± 0.02b |
Terpinolene | 12.8 | 1084 | 0.34 ± 0.04d | 0.37 ± 0.07b | 0.21 ± 0.003e | 0.20 ± 0.006f | – | – | 0.46 ± 0.03a | 0.36 ± 0.05c | – |
Linalool | 13.4 | 1098 | 0.47 ± 0.03c | 0.42 ± 0.03c | 0.43 ± 0.01c | 0.56 ± 0.01b | 0.61 ± 0.02a | 0.45 ± 0.05c | 0.44 ± 0.04c | 0.58 ± 0.04ab | 0.43 ± 0.02c |
Chrysanthenone | 14.5 | 1120 | 0.86 ± 0.01b | 0.65 ± 0.01c | 0.82 ± 0.03b | 0.99 ± 0.05a | 0.66 ± 0.10c | 0.85 ± 0.12b | 0.78 ± 0.09b | 0.50 ± 0.05d | 0.75 ± 0.05bc |
Isoborneol | 16.2 | 1155 | – | 0.53 ± 0.05a | 0.41 ± 0.04b | 0.55 ± 0.20a | 0.30 ± 0.01bc | 0.40 ± 0.03b | 0.30 ± 0.02bc | 0.22 ± 0.003c | 0.34 ± 0.03bc |
Borneol | 16.5 | 1162 | 7.85 ± 0.50de | 8.32 ± 0.97cde | 8.58 ± 0.40bcde | 9.66 ± 0.40ab | 9.13 ± 0.01bc | 10.64 ± 0.60a | 7.79 ± 0.76e | 8.02 ± 1.02cde | 9.00 ± 0.22bcd |
cis-Pinocamphone | 16.8 | 1169 | 2.73 ± 0.02c | 2.33 ± 0.06f | 2.59 ± 0.02cde | 3.42 ± 0.06a | 2.56 ± 0.06de | 2.94 ± 0.17b | 2.70 ± 0.08cd | 2.07 ± 0.11g | 2.53 ± 0.05e |
Terpinen-4-ol | 17.0 | 1173 | 1.58 ± 0.10de | 1.51 ± 0.06e | 1.91 ± 0.09bc | 2.02 ± 0.08ab | 1.84 ± 0.07bc | 2.13 ± 0.17a | 1.53 ± 0.13de | 1.50 ± 0.13e | 1.73 ± 0.09cd |
α-Terpineol | 17.7 | 1187 | 1.25 ± 0.02b | 1.35 ± 0.10a | 0.33 ± 0.005cd | 0.31 ± 0.005cde | 0.31 ± 0.01cde | 0.41 ± 0.03c | 0.23 ± 0.02e | 0.34 ± 0.11cd | 0.30 ± 0.01de |
Verbenone | 18.4 | 1202 | 9.54 ± 0.60cd | 8.68 ± 0.44d | 11.50 ± 0.42ab | 12.14 ± 1.08a | 10.56 ± 0.54bc | 9.73 ± 1.56cd | 8.74 ± 0.08d | 9.05 ± 0.50d | 10.9 ± 0.36abc |
Thymol methyl ether | 19.7 | 1232 | 1.40 ± 0.01c | 1.55 ± 0.20c | 2.11 ± 0.05b | 1.90 ± 0.12b | 1.99 ± 0.02b | 2.60 ± 0.24a | 1.37 ± 0.17c | 1.53 ± 0.25c | 2.03 ± 0.05b |
Bornyl acetate | 22.1 | 1283 | 5.56 ± 0.50de | 4.80 ± 0.21f | 7.03 ± 0.31a | 6.27 ± 0.01bc | 4.97 ± 0.26ef | 7.37 ± 0.25a | 5.90 ± 0.58cd | 4.50 ± 0.40f | 6.84 ± 0.40ab |
Thymol | 22.5 | 1292 | 0.51 ± 0.05d | 1.11 ± 0.06c | 0.24 ± 0.03e | 1.64 ± 0.05a | 1.36 ± 0.01b | 1.37 ± 0.30b | 0.56 ± 0.05d | 0.55 ± 0.03d | 0.67 ± 0.05d |
Camphor | 26.9 | 1382 | 10.35 ± 0.13cd | 9.89 ± 0.27cd | 9.52 ± 0.10d | 13.23 ± 0.31a | 11.44 ± 0.08b | 10.22 ± 0.54cd | 10.75 ± 0.92bc | 10.71 ± 1.06bc | 9.92 ± 0.27cd |
trans-Caryophyllene | 27.8 | 1413 | 2.33 ± 0.40e | 2.93 ± 0.04d | 6.30 ± 0.18a | 2.47 ± 0.28de | 3.50 ± 0.05c | 6.66 ± 0.74a | 2.37 ± 0.12de | 2.44 ± 0.01de | 5.61 ± 0.12b |
Caryophyllene oxide | 34.4 | 1577 | 0.72 ± 0.08de | 0.56 ± 0.03e | 1.52 ± 0.05b | 0.84 ± 0.01d | 0.61 ± 0.09e | 1.78 ± 0.28a | 0.69 ± 0.03de | 0.27 ± 0.02f | 1.03 ± 0.02c |
Monoterpene hydrocarbons |  |  | 33.36 ± 2.41a | 34.36 ± 0.50a | 24.80 ± 0.09b | 18.98 ± 1.32c | 25.06 ± 0.66b | 20.31 ± 2.53c | 32.23 ± 2.75a | 34.83 ± 2.00a | 27.2 ± 1.27b |
Oxygenated monoterpenes |  |  | 42.08 ± 1.89d | 41.57 ± 0.95d | 45.81 ± 0.11c | 52.95 ± 2.23a | 45.72 ± 0.62c | 49.4 ± 0.88b | 41.08 ± 2.67d | 39.56 ± 2.53d | 45.4 ± 1.29c |
Sesquiterpene hydrocarbons |  |  | 2.33 ± 0.39e | 2.93 ± 0.40d | 6.29 ± 0.17a | 2.47 ± 0.28de | 3.50 ± 0.05c | 6.66 ± 0.74a | 2.37 ± 0.12de | 2.44 ± 0.10de | 5.61 ± 0.12b |
Oxygenated sesquiterpenes |  |  | 0.72 ± 0.81de | 0.56 ± 0.31e | 1.52 ± 0.004b | 0.84 ± 0.015d | 0.61 ± 0.09e | 1.78 ± 0.28a | 0.69 ± 0.03de | 0.27 ± 0.02f | 1.03 ± 0.02c |
Other compounds |  |  | 6.07 ± 0.42a | 4.49 ± 0.40c | 2.65 ± 0.12e | 4.65 ± 0.20bc | 3.88 ± 0.18d | 2.57 ± 0.43e | 5.91 ± 0.50a | 5.08 ± 0.06b | 3.04 ± 0.05e |
Total |  |  | 84.57 ± 0.48a | 83.9 ± 0.56a | 81.06 ± 0.10c | 79.9 ± 0.96d | 78.76 ± 0.18e | 80.73 ± 1.06cd | 82.3 ± 0.44b | 82.19 ± 0.70b | 82.3 ± 0.10b |