Table 1 Concentration of major (%), trace, and rare earth elements (ppm) of the studied carbonate rocks as well as ratios

26.62

25.73

27.1

25.94

27.54

25.41

24.95

27.8

24.95

27.8

26.39

1.77

1.81

1.54

0.94

1.99

2.1

2.4

2.5

0.94

2.5

1.88

26.75

26.63

25.31

27.37

25.14

24.7

26.4

25.1

24.7

27.37

25.93

10.2

10.15

10.54

10.94

12.15

9.85

11.2

10.34

9.85

12.15

10.67

3.39

3.45

2.97

3.54

2.15

3.41

3.2

2.94

2.15

3.54

3.13

0.26

2.58

1.37

0.94

1.04

0.27

1.94

1.64

0.26

2.58

1.26

0.71

0.62

0.82

0.74

0.51

0.75

0.84

0.56

0.51

0.84

0.69

0.37

0.37

0.36

0.35

0.41

0.41

0.52

0.31

0.31

0.52

0.39

0.68

0.67

0.65

0.61

0.75

0.81

0.75

0.67

0.61

0.81

0.70

0.115

0.114

0.12

0.12

0.18

0.13

0.12

0.14

0.114

0.18

0.13

0.67

0.74

0.69

0.79

0.54

0.84

0.65

0.85

0.54

0.85

0.72

0.11

0.12

0.1

0.11

0.17

0.16

0.18

0.18

0.1

0.18

0.14

28.2

26.91

17.92

27.01

27.41

31.12

26.82

26.93

17.92

31.12

26.54

8.1

8.28

7.04

4.3

9.1

9.61

10.98

11.44

4.3

11.44

8.61

53.4

60

80

80.1

95

92

97

100

53.4

100

82.19

59.6

50.3

60.4

40.6

71.2

75

78

80

40.6

80

64.39

238.8

250.1

325.4

280.1

310

315

340

384

238.8

384

305.43

5.6

6.7

5.8

7.1

8.4

6.8

7.9

8.9

5.6

8.9

7.15

47.2

50.3

61.4

62.8

71.52

68

79

90

47.2

90

66.28

10.1

10.5

12.4

15.3

16.4

15.2

17.3

17.9

10.1

17.9

14.39

109.1

120

112.8

151.2

165

105

164

134

105

165

132.64

3.5

4.2

5.7

5.9

6.2

4.8

6.4

7.9

3.5

7.9

5.58

129.4

135.1

140.8

159

145

159

164

179

129.4

179

151.41

7.6

8.6

9.1

10.1

12

11.4

12.9

16.1

7.6

16.1

10.98

19

20

25

30

24

26

29

32

19

32

25.63

11.4

12.5

14.3

12.3

13.7

13.2

14.2

15.4

11.4

15.4

13.38

2

3

3

4

5

3

4

6

2

6

3.75

2.5

3

4

5.5

5.4

3.1

4.7

4.5

2.5

5.5

4.09

19.1

20.2

19.8

24.3

27.4

20.4

24.1

28.5

19.1

28.5

22.98

13.7

15.4

16.2

14.8

17.2

18.7

15.4

16.4

13.7

18.7

15.98

3.9

4.5

6.2

4.8

7.1

5.4

4.7

7.5

3.9

7.5

5.51

2.1

2.5

2.3

3.7

3.9

3.1

4.2

3.8

2.1

4.2

3.20

4.1

4.5

5.1

4.8

5.7

2.5

3.1

3.8

2.5

5.7

4.20

23

25

27

29

30

29

25

34

23

34

27.75

7

8

6

9

8

8

7

8

6

9

7.63

162.7

170.5

180.3

185

190

189

172

201

162.7

201

181.31

27.4

28.5

29

30

35

37

25

40

25

40

31.49

13.1

15.2

12.4

13.9

16.7

14.8

15.1

17.2

12.4

17.2

14.80

17.4

18.4

20.3

19.7

21.8

19.9

20.2

22.7

17.4

22.7

20.05

0.3

0.4

0.3

0.5

0.6

0.4

0.5

0.6

0.3

0.6

0.45

24

22

27

26

27

31

32

35

22

35

28.00

15.8

16.8

17.6

17.9

18.4

18.1

14.9

19.2

14.9

19.2

17.34

2

2

3

2

2

2

3

3

2

3

2.38

15

18

19

22

25

26

25

27

15

27

22.13

1.1

1.3

1.7

2.1

2.3

2.1

2.4

3.4

1.1

3.4

2.05

8.6

7.9

9.3

10.2

10.4

9.4

8.4

10.8

7.9

10.8

9.38

4

3

2

4

4

3

4

4

2

4

3.50

0.31

0.31

0.3

0.36

0.37

0.44

0.38

0.43

0.31

0.43

0.37

15.26

14.29

14.04

13.58

15.32

19.17

15.16

12.66

15.26

12.66

14.74

0.47

0.54

0.57

0.66

0.57

0.55

0.55

0.56

0.57

0.56

0.60

84.30

92.60

95.00

97.90

112.20

110.90

99.50

122.30

84.3

122.3

101.84

43.10

42.20

46.80

50.30

54.40

51.40

56.10

63.50

42.2

63.5

50.98

366.50

390.40

412.80

429.20

459.90

444.60

414.10

493.60

366.5

493.6

426.39

1.83

1.58

1.53

1.36

1.40

1.42

1.00

1.48

1.67

1.48

1.42